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Sia

青州's Question
Chemistry
Posted 7 months ago

1. Which of the following reactions are spontaneous at standard state? (Consult table of electrode potentials.)
A) \mathrm{I}_{2}+2 \mathrm{Fe}^{2+} 3 / 4 ® 2 \mathrm{I}^{-}+2 \mathrm{Fe}^{3+}
B) 8H++2NO3++3Cu(s)3/4R2NO(g)+3Cu2++4H2O8 \mathrm{H}^{+}+2 \mathrm{NO}_{3}^{-+}+3 \mathrm{Cu}_{(\mathrm{s})} 3 / 4 \mathbb{R}_{2} \mathrm{NO}_{(\mathrm{g})}+3 \mathrm{Cu}^{2+}+4 \mathrm{H}_{2} \mathrm{O}
C) 4MnO4++12H+3/4R4Mn2++5O2+6H2O4 \mathrm{MnO}_{4}^{-+}+12 \mathrm{H}^{+} 3 / 4 \mathrm{R}_{4} \mathrm{Mn}^{2+}+5 \mathrm{O}_{2}+6 \mathrm{H}_{2} \mathrm{O}
D) \mathrm{Cu}_{(\mathrm{s})}+\mathrm{Cl}_{2(\mathrm{~g})} 3 / 4 ® \mathrm{Cu}^{2+}(\mathrm{aq})+2 \mathrm{Cl}_{(\mathrm{aq})}
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Answer from Sia
Posted 7 months ago
D
Key Concept
Spontaneity and Electrode Potentials
Explanation
A spontaneous reaction at standard state occurs when the overall cell potential is positive. This is determined by looking up the standard electrode potentials for the half-reactions and calculating the standard cell potential (E°cell). If E°cell is positive, the reaction is spontaneous.

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