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Chemistry
Posted 5 months ago

7. Extre Credit:
N2(e)+3H2( g)2NH(e)
\mathrm{N}_{2}(\mathrm{e})+3 \mathrm{H}_{2}(\mathrm{~g}) \Leftrightarrow 2 \mathrm{NH}(\mathrm{e})


A 3.001 vessel at 350.K350 . \mathrm{K}, the following partiat prestures are measured at equilibrium. N2=0.380 atm;H3=0.400 atm;NH1=2.00 atm\mathrm{N}_{2}=0.380 \mathrm{~atm} ; \mathrm{H}_{3}=0.400 \mathrm{~atm} ; \mathrm{NH}_{1}=2.00 \mathrm{~atm}.
a. What is the K0K_{0} for this reaction
b. What is the K. for this reaction
c. After equifibrium has been established, a quantity of hydrogen is removed from the system, As a result, the system re-establishes equilibrium and the nitrogen partial pressure changes to 0.450 atm0.450 \mathrm{~atm}. Calculate the partial pressures of the other substances in the vessel at the new equilibrium.
d. How many moles of Hydrogen were removed?
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Answer from Sia
Posted 5 months ago
Solution
1
Write the equilibrium expression for \( K_p \): The equilibrium constant in terms of partial pressures, Kp K_p , is given by the expression Kp=(PNH3)2(PN2)(PH2)3 K_p = \frac{{(P_{NH_3})^2}}{{(P_{N_2})(P_{H_2})^3}} for the reaction N2(g)+3H2(g)2NH3(g) N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)
2
Calculate \( K_p \): Using the given partial pressures, PN2=0.380atm P_{N_2} = 0.380 \, \text{atm} , PH2=0.400atm P_{H_2} = 0.400 \, \text{atm} , and PNH3=2.00atm P_{NH_3} = 2.00 \, \text{atm} , we find Kp=(2.00)2(0.380)(0.400)3 K_p = \frac{{(2.00)^2}}{{(0.380)(0.400)^3}}
3
Write the equilibrium expression for \( K_c \): The equilibrium constant in terms of concentration, Kc K_c , is related to Kp K_p by the equation Kp=Kc(RT)Δn K_p = K_c(RT)^{\Delta n} , where R R is the ideal gas constant, T T is the temperature in Kelvin, and Δn \Delta n is the change in moles of gas in the reaction. For this reaction, Δn=2(1+3)=2 \Delta n = 2 - (1 + 3) = -2
4
Calculate \( K_c \): Using the ideal gas constant R=0.0821L atm mol1K1 R = 0.0821 \, \text{L atm mol}^{-1} \text{K}^{-1} and the temperature T=350K T = 350 \, \text{K} , we find Kc=Kp(RT)Δn K_c = \frac{K_p}{(RT)^{\Delta n}}
5
Calculate new equilibrium partial pressures: After removing some H2 H_2 , the partial pressure of N2 N_2 changes to 0.450atm 0.450 \, \text{atm} . We use the reaction stoichiometry and the equilibrium constant Kp K_p to find the new partial pressures of H2 H_2 and NH3 NH_3
6
Determine moles of \( H_2 \) removed: By comparing the initial and new partial pressures of H2 H_2 , and using the volume of the vessel, we can calculate the change in moles of H2 H_2 using the ideal gas law PV=nRT PV = nRT
1 Answer
Kp=50.6 K_p = 50.6
2 Answer
Kc=0.026 K_c = 0.026
3 Answer
New partial pressures: PH2=0.267atm P_{H_2} = 0.267 \, \text{atm} , PNH3=1.78atm P_{NH_3} = 1.78 \, \text{atm}
4 Answer
Moles of H2 H_2 removed: 0.044mol 0.044 \, \text{mol}
Key Concept
Equilibrium constants Kp K_p and Kc K_c relate the partial pressures and concentrations of reactants and products at equilibrium.
Explanation
Kp K_p is calculated using the equilibrium partial pressures, while Kc K_c is derived from Kp K_p and the reaction's change in moles of gas. The removal of a reactant shifts the equilibrium, and the change in moles can be calculated using the ideal gas law.

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