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Question
Chemistry
Posted 4 months ago

8. Which of the following fragment ion would show the strongest peak in an EI-MS of 2 -methylpentane?
A)
[C6H14][\mathrm{C} 6 \mathrm{H} 14]^{-}
в) [[ C5H 511 ]
C) [C4H9][\mathrm{C} 4 \mathrm{H} 9]
D) [C3H7+\left[\left.\mathrm{C} 3 \mathrm{H}_{7}\right|^{+}\right.
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Answer from Sia
Posted 4 months ago
C
Key Concept
Stability of carbocations
Explanation
In electron ionization mass spectrometry, the most stable fragment ion typically shows the strongest peak. The [C4H9]+ ion forms a more stable secondary carbocation compared to the other options, which leads to a stronger signal in the mass spectrum.

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