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15240672380's Question
Chemistry
Posted 8 months ago

A) For hydrogen, many electronic transitions from n>2n>2 to n=2n=2 (Balmer series) emit photons which are in the visible range of the electromagnetic spectrum.
Demonstrate whether a photon emitted from the electronic transition n=3\mathrm{n}=3 to n=2\mathrm{n}=2 for the Li2+ ion is also in the visible range of the spectrum (i.e. between 400 and 700 nm).
B) Calculate the ionization energy for the remaining electron of Li2+.
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Answer from Sia
Posted 8 months ago
Solution
1
Use the Rydberg formula for hydrogen-like ions: The wavelength of light emitted during electronic transitions can be calculated using the modified Rydberg formula for hydrogen-like ions: λ=n2hcZ2RH(n2n02) \lambda = \frac{n^2 h c Z^2}{R_H (n^2 - n_0^2)} , where nn is the initial energy level, n0n_0 is the final energy level, hh is Planck's constant, cc is the speed of light, ZZ is the atomic number, and RHR_H is the Rydberg constant for hydrogen
2
Calculate the wavelength for Li2+ transition: For the Li2+ ion (Z=3Z=3), the transition is from n=3n=3 to n=2n=2. Plugging these values into the Rydberg formula gives us the wavelength of the emitted photon
3
Determine if the wavelength is in the visible range: Compare the calculated wavelength to the visible range of the electromagnetic spectrum (400 to 700 nm) to determine if the photon is visible
A Answer
[Insert final answer for Problem A here]
Key Concept
Rydberg formula for hydrogen-like ions
Explanation
The Rydberg formula is used to calculate the wavelength of emitted photons during electronic transitions in hydrogen-like ions.
1
Use the ionization energy formula for hydrogen-like ions: The ionization energy for a hydrogen-like ion can be calculated using the formula: E=Z2RHhcn2E = \frac{Z^2 R_H h c}{n^2}, where ZZ is the atomic number, RHR_H is the Rydberg constant for hydrogen, hh is Planck's constant, cc is the speed of light, and nn is the principal quantum number of the electron being removed
2
Calculate the ionization energy for Li2+: For the Li2+ ion (Z=3Z=3) with the electron in the ground state (n=1n=1), plug these values into the formula to find the ionization energy
B Answer
[Insert final answer for Problem B here]
Key Concept
Ionization energy for hydrogen-like ions
Explanation
The ionization energy formula is used to calculate the energy required to remove an electron from a hydrogen-like ion.

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