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Question
Chemistry
Posted 9 months ago

Consider a hypothetical element, Z, which has an atomic number of 122 and is located in a newly discovered row of the periodic table. Element ZZ forms an oxide, ZO_3, which exhibits both ionic and covalent character. The oxide is a solid at room temperature and has a high melting point. In the context of modern chemical theories, which of the following statements is most likely to be true about the bonding and structure of ZO_3? Options: a) ZO_3 has a molecular structure with sp2\mathrm{sp}^{\wedge} 2 hybridization in Z\mathrm{Z} and forms a lattice similar to silicon dioxide. b) ZO_3 forms a polymeric structure with resonance-stabilized Z-O bonds and has sp3\mathrm{sp}^{\wedge} 3 hybridization in Z. c) ZO_3 exhibits a metallic bonding character due to the delocalization of electrons from ZZ to the oxygen atoms. d) ZO_3 has an ionic lattice with partial covalent character, where Z\mathrm{Z} exhibits an oxidation state uncommon for its period.
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Answer from Sia
Posted 9 months ago
B
Key Concept
Hybridization and Polymeric Structure
Explanation
Given the high atomic number of Z (122), it is likely to have access to d and f orbitals, allowing for expanded octets and multiple bonding scenarios. The description of ZO_3 suggests a polymeric structure with resonance stabilization, which is consistent with sp3\mathrm{sp}^3 hybridization in Z, as this allows for tetrahedral coordination and resonance in structures similar to phosphates or sulfates.

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