Asksia AI LOGO

Sia

Question
Chemistry
Posted 6 months ago

Predict the products of the following reactions. If the reaction is an acid-base reaction, predict its position of equilibrium.
(a)
+CH3ONa++\mathrm{CH}_{3} \mathrm{O}^{-} \mathrm{Na}^{+}
(b)
Sign in to unlock the answer
Answer from Sia
Posted 6 months ago
Solution
1
Identify the reactants: The six-membered ring structure with an SH group is a thiol, and it is reacting with methoxide ion (CH3O\mathrm{CH_3O^-}) from sodium methoxide (CH3ONa\mathrm{CH_3ONa})
2
Predict the reaction type: The reaction between a thiol and a methoxide ion is likely to be a nucleophilic substitution, where the methoxide ion acts as the nucleophile
3
Determine the product: The methoxide ion will attack the sulfur atom of the thiol, leading to the formation of a thioether as the product. The chemical equation for the reaction is: RSH+CH3ORSCH3+OH\mathrm{R-SH} + \mathrm{CH_3O^-} \rightarrow \mathrm{R-S-CH_3} + \mathrm{OH^-}
4
Acid-base reaction equilibrium: Since thiols are weak acids and methoxide is a strong base, the equilibrium will lie to the right, favoring the formation of the thioether and hydroxide ion
1 Answer
The product of reaction (a) is a thioether (RSCH3\mathrm{R-S-CH_3}) and hydroxide ion (OH\mathrm{OH^-}), with the equilibrium position favoring the product side.
Key Concept
Nucleophilic substitution reactions involve the attack of a nucleophile on an electrophilic center, leading to the replacement of a leaving group.
Explanation
In this case, the methoxide ion acts as a nucleophile and attacks the electrophilic sulfur atom of the thiol, replacing the hydrogen atom and forming a thioether.
1
Identify the reactant: The bicyclic organic compound with multiple sulfur atoms is likely a polysulfide or a compound with a similar structure
2
Predict the reaction type: The label "reduction" suggests that the reaction involves the gain of electrons or a decrease in the oxidation state of the sulfur atoms
3
Determine the product: The reduction of a polysulfide typically involves the conversion of sulfur-sulfur bonds into sulfide ions or hydrogen sulfide, depending on the reducing agent and reaction conditions
2 Answer
The product of reaction (b) is likely to be a compound with a lower oxidation state of sulfur, such as sulfide ions (S2\mathrm{S^{2-}}) or hydrogen sulfide (H2S\mathrm{H_2S}), depending on the specific reactant and reducing agent used.
Key Concept
Reduction reactions involve the gain of electrons or a decrease in the oxidation state of an element.
Explanation
In the reduction of a polysulfide, the sulfur atoms undergo a decrease in oxidation state, leading to the formation of sulfide ions or hydrogen sulfide.

Not the question you are looking for? Ask here!

Enter question by text

Enter question by image

Upgrade to Asksia Pro

Join a AskSia's Pro Plan, and get 24/7 AI tutoring for your reviews, assignments, quizzes and exam preps.

Unlimited chat query usages
Strong algorithms that better know you
Early access to new release features
Study Other Question