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Question
Chemistry
Posted 7 months ago
Q2. In a vacuum chamber of 0.01 atm0.01 \mathrm{~atm}, the air is heated to 3000 K3000 \mathrm{~K}. Determine convertion ratio of NO at chemical equilibrium state?
 Air at 0.01 atm,3000 KO2+3.76 N2 aˋ xNO+(1x/2)O2+(3.76x/2)N2x=?
\begin{array}{l}
\text { Air at } 0.01 \mathrm{~atm}, 3000 \mathrm{~K} \\
\mathrm{O}_{2}+3.76 \mathrm{~N}_{2} \text { à } \mathrm{xNO}+(1-\mathrm{x} / 2) \mathrm{O}_{2}+ \\
(3.76-\mathrm{x} / 2) \mathrm{N}_{2} \\
\mathrm{x}=?
\end{array}
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Answer from Sia
Posted 7 months ago
Solution
1
Write the balanced chemical equation: The formation of NO from air components involves the reaction of nitrogen and oxygen. The balanced equation for the formation of NO is N2+O22NON_2 + O_2 \rightarrow 2NO
2
Set up the equilibrium expression: For the reaction N2+O22NON_2 + O_2 \rightarrow 2NO, the equilibrium constant expression is K=[NO]2[N2][O2]K = \frac{[NO]^2}{[N_2][O_2]}
3
Express concentrations in terms of x: Let x be the conversion ratio of NO at equilibrium. The initial moles of O2O_2 and N2N_2 are in the ratio of 1:3.76. At equilibrium, the moles of NONO will be 2x2x, O2O_2 will be 1x21 - \frac{x}{2}, and N2N_2 will be 3.76x23.76 - \frac{x}{2}
4
Apply the ideal gas law: Since the reaction is in a vacuum chamber at 0.01 atm0.01 \mathrm{~atm} and 3000 K3000 \mathrm{~K}, we can assume that the volume is constant and the partial pressures are proportional to the mole fractions. Thus, PNO=2xPtotalP_{NO} = 2xP_{total}, PO2=(1x2)PtotalP_{O_2} = (1 - \frac{x}{2})P_{total}, and PN2=(3.76x2)PtotalP_{N_2} = (3.76 - \frac{x}{2})P_{total}
5
Calculate the equilibrium constant K: The value of K for the formation of NO at 3000 K3000 \mathrm{~K} needs to be known or given to solve for x. Assuming K is known, we can substitute the partial pressures into the equilibrium expression to solve for x
6
Solve for x: Substitute the expressions for PNOP_{NO}, PO2P_{O_2}, and PN2P_{N_2} into the equilibrium constant expression and solve for x. This will require algebraic manipulation and possibly numerical methods if the equation is not easily solvable by hand
Answer
The conversion ratio of NO at chemical equilibrium state, x, is calculated by solving the equilibrium constant expression with the given conditions. The exact value of x depends on the known value of the equilibrium constant K at 3000 K3000 \mathrm{~K}.
Key Concept
Equilibrium constant expression
Explanation
The conversion ratio of NO at equilibrium can be determined by using the equilibrium constant expression, which relates the partial pressures of the reactants and products at equilibrium.

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