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青州's Question
Chemistry
Posted 7 months ago

What is the minimum uncertainty in a helium atom's velocity ( Delta v minv \mathrm{~min} ) if the position is known within 1.4dotA1.4 \operatorname{dot} \mathrm{A}.
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Answer from Sia
Posted 7 months ago
Solution
1
Identify the given data: The position uncertainty Δx\Delta x is given as 1.4A˚1.4 \, \text{Å} (angstroms)
2
Recall Heisenberg's Uncertainty Principle: The principle states that ΔxΔp2\Delta x \cdot \Delta p \geq \frac{\hbar}{2}, where Δp\Delta p is the uncertainty in momentum and \hbar is the reduced Planck's constant (=h2π\hbar = \frac{h}{2\pi})
3
Express momentum uncertainty in terms of velocity: Since momentum p=mvp = m \cdot v, the uncertainty in momentum Δp=mΔv\Delta p = m \cdot \Delta v. Therefore, ΔxmΔv2\Delta x \cdot m \cdot \Delta v \geq \frac{\hbar}{2}
4
Solve for velocity uncertainty: Rearrange the equation to find Δv\Delta v: Δv2mΔx\Delta v \geq \frac{\hbar}{2m \Delta x} For a helium atom, the mass mm is approximately 4×1.66×1027kg4 \times 1.66 \times 10^{-27} \, \text{kg}
5
Substitute the values: Δv1.054×1034Js2×4×1.66×1027kg×1.4×1010m\Delta v \geq \frac{1.054 \times 10^{-34} \, \text{Js}}{2 \times 4 \times 1.66 \times 10^{-27} \, \text{kg} \times 1.4 \times 10^{-10} \, \text{m}} Calculate the result to find the minimum uncertainty in velocity
Answer
The minimum uncertainty in the helium atom's velocity is approximately 1.4×103m/s1.4 \times 10^3 \, \text{m/s}.
Key Concept
Heisenberg's Uncertainty Principle
Explanation
The principle states that the product of the uncertainties in position and momentum of a particle is always greater than or equal to 2\frac{\hbar}{2}. By knowing the position uncertainty, we can calculate the minimum uncertainty in velocity.

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