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Chemistry
Posted 7 months ago
if i want to use Ag nanomaterial to do a photochemistry reations to have a catalyst hydrogenation of ketone, please propose the mechanism by reaction arrow pushing
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Answer from Sia
Posted 7 months ago
Solution
1
Formation of Ag-H species: Silver nanoparticles (Ag) can absorb light and generate electrons and holes. The electrons can reduce protons (H⁺) from the solvent or from a sacrificial donor to form Ag-H species
2
Transfer of hydrogen: The Ag-H species can then transfer a hydrogen atom to the ketone, resulting in the formation of a radical intermediate on the ketone
3
Radical recombination: The radical intermediate can abstract a hydrogen atom from another Ag-H species or from the solvent, leading to the formation of the secondary alcohol and regenerating the Ag nanoparticle catalyst
Answer
The mechanism involves the formation of Ag-H species, transfer of hydrogen to the ketone to form a radical intermediate, and radical recombination to produce the secondary alcohol while regenerating the Ag catalyst.
Key Concept
Photochemical hydrogenation of ketones using Ag nanomaterials involves the generation of Ag-H species and radical intermediates.
Explanation
The Ag nanoparticles act as a catalyst by creating reactive hydrogen species upon light absorption, which then hydrogenate the ketone to form an alcohol.

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